The influence of electrolytes on gaseous monolayers I. Neutral films

Autor:	Eric Keightley Rideal, J. N. Phillips
Rok vydání:	1955
Předmět:	General Energy Chemistry Monolayer Cationic polymerization Analytical chemistry Organic chemistry Penetration (firestop) Electrolyte Surface pressure Anionic detergent Ion
Zdroj:	Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 232:149-158
ISSN:	2053-9169 0080-4630
Popis:	An equimolar mixture of a long-chain cationic and anionic detergent when spread on dilute substrates at the oil/water interface has been shown to obey the theoretical relationship II( A – A 0 ) = kT . However, on concentrated substrates this relationship is no longer obeyed and the increased surface pressure observed has been attributed to a nonspecific penetration of the interface by the substrate ions. Good agreement has been obtained between the number of penetrating ions calculated from the increased surface pressure found on concentrated substrates and the number calculated directly using a modified Stem treatment.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::828dc37bb90ed0c6c3ddc3bdcf9b4304 https://doi.org/10.1098/rspa.1955.0207 Zobrazit plný text záznamu