Tertiary Amines in Acyl Transfer Reactions

Autor:	E. M. Cherkasova, S. V. Bogatkov, Z. P. Golovina
Rok vydání:	1977
Předmět:	Solvent Reaction rate Acylation Chemistry Intramolecular force Kinetics Intermolecular force Organic chemistry lipids (amino acids peptides and proteins) Amine gas treating General Chemistry Catalysis
Zdroj:	Russian Chemical Reviews. 46:246-263
ISSN:	1468-4837 0036-021X
Popis:	The mechanism and kinetics of acyl transfer reactions in the presence of tertiary amines are examined and the quantitative relations between the rate of reaction and the structure of the acylating agent, the acylated substrate, the amine, and the solvent, temperature, and the ratio of the efficiencies of intramolecular and intermolecular catalysis are discussed. A number of examples of the application of tertiary amines as accelerators of acyl transfer reactions, which are of practical importance, are presented. The bibliography includes 282 references.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::828d9579576c8929a337d1642b9a86b4 https://doi.org/10.1070/rc1977v046n03abeh002130 Zobrazit plný text záznamu