Si–C(sp3) bond activation through oxidative addition at a Rh(i) centre

Autor:	Antonio J. Martínez-Martínez, Miguel A. Huertos, Susan Azpeitia, Andrew S. Weller, María A. Garralda
Rok vydání:	2020
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Cationic polymerization Halide Medicinal chemistry Oxidative addition Silane Bond cleavage Extractor
Zdroj:	Dalton Transactions. 49:5416-5419
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d0dt00725k
Popis:	An easy, direct and room temperature silicon-carbon bond activation is reported. The reaction of [RhCl(coe)2]2 with the silane Si(Me)2(o-C6H4SMe)2 in the presence of an halide extractor provokes a Si-CH3 bond cleavage yielding a cationic silyl-methyl-Rh(iii). In contrast, if the reaction is performed using the Rh(i) bis-alkene dimers, [RhCl(cod)]2 or [RhCl(nbd)]2, the Si-CH3 bond activation does not occur.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8282ee9971ce2ee7b7b2d3785b0e3267 https://doi.org/10.1039/d0dt00725k Zobrazit plný text záznamu