Large-ring complexes formed from diacetylene diphosphines of the type But2PCC[CH2]nCCPBut2(n= 4 or 5); X-ray structure of [IrCl(CO){But2PCC[CH2]5CCPBut2}]

Autor:	Geoffrey A. Williams, Ronald P. Mason, Eric Mentzer, H. David Empsall, David Pawson, Bernard L. Shaw
Rok vydání:	1977
Předmět:	Diacetylene Stereochemistry chemistry.chemical_element Halide Type (model theory) Ring (chemistry) chemistry.chemical_compound Crystallography chemistry Diphosphines Molecular Medicine Iridium Platinum Palladium
Zdroj:	J. Chem. Soc., Chem. Commun.. :311-313
ISSN:	0022-4936
DOI:	10.1039/c39770000311
Popis:	Diacetylene diphosphines of the type But2PCC[CH2]nCCPBut2(n= 4 or 5) give, with iridium halogeno–carbonyls, large-ring mono- or bi-nuclear species and the X-ray structure of trans-[IrCl(CO){But2PCC[CH2]5CCPBut2}] is reported; with platinum or palladium halides very large-ring polynuclear species are formed, e.g. a 72-atom ring in [PtCl2{But2PCC[CH2]5CCPBut2}]6.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::827e603da2f59fb39a04df588da1705b https://doi.org/10.1039/c39770000311 Zobrazit plný text záznamu