Diazabutadienes as σ,π-bridging ligands in binuclear molybdenum carbonyl complexes containing molybdenummolybdenum double bonds

Autor:	Kees Vrieze, Ad Oskam, L.H. Staal
Rok vydání:	1978
Předmět:	Inorganic Chemistry chemistry.chemical_classification Crystallography Double bond chemistry Molybdenum Organic Chemistry Materials Chemistry chemistry.chemical_element Physical and Theoretical Chemistry Photochemistry Biochemistry
Zdroj:	Journal of Organometallic Chemistry. 145:C7-C10
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)84083-8
Popis:	Reduction of Mo(CO)4 DAB (DAB = diazabutadiene) followed by oxidation with Mn(CO)3BrDAB or HCl gives a small yield (15 to 25%) of complexes of the type Mo2(CO)6(DAB)2, in which the two DAB ligands bridge a molybdenummolybdenum double bond and act as σ,π-donors.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::82693d0c3f488b4bc905c44c77dcf6dc https://doi.org/10.1016/s0022-328x(00)84083-8 Zobrazit plný text záznamu