ChemInform Abstract: Novel Hydroborating Agents from Silylamine-Boranes

Autor:	John A. Soderquist, Ramon Huertas, Jesus R. Medina
Rok vydání:	2010
Předmět:	Hydrolysis Broad spectrum chemistry.chemical_compound Hydroboration Aqueous solution Water soluble chemistry Organic chemistry Boranes General Medicine Borane Diborane
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199844077
Popis:	Exhibiting a broad spectrum of hydroboration reactivities, seven (7) new silylamine-borane complexes ( 1 ) were efficiently prepared from diborane and the corresponding silylated amines ( 2 ). Most are crystalline solids which are air-stable, concentrated borane sources. All provide convenient alternatives to other hydroborating agents, 2 undergoing complete hydrolysis to volatile and/or water soluble by-products upon aqueous work-up, thereby greatly facilitating the isolation of the borane-derived reaction products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::82672d32586708a34fd9d71de0a0daa3 https://doi.org/10.1002/chin.199844077 Zobrazit plný text záznamu Plný text