Vibrational relaxation in hydrogen bonded systems
Autor: | P. C. M. van Woerkom, J. De Bleijser, H.S. Kielman, D. van Duijn, J. C. Leyte |
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Rok vydání: | 1976 |
Předmět: | |
Zdroj: | Chemical Physics. 13:403-415 |
ISSN: | 0301-0104 |
Popis: | Experimental results are presented, supporting the theory presented earlier. These results, obtained by studying the shape of the as. OCO stretching band of acetate ions in CH3OH and deuterated analogs, show vibrational relaxation by near-resonant vibrational energy transfer to the solvent. The essential role of the H-bond in this process, as derived theoretically, is borne out by the results. |
Databáze: | OpenAIRE |
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