Vibrational relaxation in hydrogen bonded systems

Autor: P. C. M. van Woerkom, J. De Bleijser, H.S. Kielman, D. van Duijn, J. C. Leyte
Rok vydání: 1976
Předmět:
Zdroj: Chemical Physics. 13:403-415
ISSN: 0301-0104
Popis: Experimental results are presented, supporting the theory presented earlier. These results, obtained by studying the shape of the as. OCO stretching band of acetate ions in CH3OH and deuterated analogs, show vibrational relaxation by near-resonant vibrational energy transfer to the solvent. The essential role of the H-bond in this process, as derived theoretically, is borne out by the results.
Databáze: OpenAIRE