Estimate of the Decay Rate Constant of Hydrogen Sulfide from Drywall in a Simulated Bench-Scale Study
| Autor: | Amro El Badawy, David A. Carson, Thabet Tolaymat |
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| Rok vydání: | 2013 |
| Předmět: |
Environmental Engineering
Materials science Environmental engineering Mechanics Decomposition Reaction rate constant Volume (thermodynamics) Particle-size distribution Environmental Chemistry Particle Drywall Particle size Exponential decay General Environmental Science Civil and Structural Engineering |
| Zdroj: | Journal of Environmental Engineering. 139:538-544 |
| ISSN: | 1943-7870 0733-9372 |
| DOI: | 10.1061/(asce)ee.1943-7870.0000609 |
| Popis: | Research was conducted to investigate the impact of particle size on H2S gas emissions and estimate a decay rate constant for H2S gas generation from the anaerobic decomposition of drywall. Three different particle sizes of regular drywall and one particle size of paperless drywall were evaluated. The experiment was conducted in a carbon-limited environment. The paperless drywall generated significantly less H2S gas than regular drywall at the same particle size. No significant differences were found between the rates of H2S gas generated from the different particle sizes of regular drywall investigated (p=0.44), which most likely was the result of the carbon limitation. The volume of H2S gas emitted from drywall was modeled as a first-order decay with correction factors that take into account the impacts of pH, temperature, and liquid-gas partitioning. The first-order decay model resulted in an average decay constant value of 0.14±0.01 and 0.031 year−1 for regular and paperless drywall, respecti... |
| Databáze: | OpenAIRE |
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