Some unexpected reactions involving diphenylketene

Autor:	Stanley M. Roberts, Russell J. Thomas, Robert J. Pryce, Julian O. Williams, Carlos A. Pittol, Rakesh Maurya
Rok vydání:	1992
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Bicyclic molecule Enol ether chemistry.chemical_element Ketene Organic chemistry Nitrogen Diphenylketene Cycloaddition
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :1617
ISSN:	1364-5463 0300-922X
DOI:	10.1039/p19920001617
Popis:	Diphenylketene reacted with the 2-azabicyclo[2.2.1]hept-5-enes 5, 6 and 10 by attack on nitrogen to give the piperidones 7, 8 and the cyclopentenols 11 respectively. The same ketene reacted with the cyclohexa-1,3-dienes 16 and 17 to give significant amounts of the [4 + 2] addition products 20 and 21 respectively. The initially formed product from the cycloaddition of the enol ether 23 and diphenylketene is unstable, rearranging to produce the unsaturated ester 24.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8207a3c925b16c7589bfb41ecda92a51 https://doi.org/10.1039/p19920001617 Zobrazit plný text záznamu