β-(1,10-Phenanthroline)(1,3-propanediamine-N,N'-diacetato)cobalt(III) Chloride Trihydrate

Autor:	W. T. Robinson, Shane G. Telfer, Richard M. Hartshorn
Rok vydání:	1997
Předmět:	Stereochemistry Ligand Phenanthroline chemistry.chemical_element General Medicine Crystal structure Medicinal chemistry General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound chemistry Octahedral molecular geometry Carboxylate Hydrate Cobalt Cis–trans isomerism
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 53:1757-1759
ISSN:	0108-2701
DOI:	10.1107/s0108270197010755
Popis:	The crystal structure of [Co(C 7 H 12 N 2 O 4 )(C 12 H 8 N 2 )]-Cl.3H 2 O is the first reported structure of a cobalt complex with the tetradentate 1,3-propanediamine-N,N'-diacetato ligand and it has adopted a β unsymmetrical cis configuration. The phenanthroline fills the two remaining coordination sites to give an approximately octahedral geometry around the Co atom.
Databáze:	OpenAIRE
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