Self‐Assembly of Stereoselective, Mononuclear, Triple‐Stranded Helicate Complexes ML 3 with Trivalent Scandium and Lanthanide Metal Ions − Quantitative Transmetallation of the Lanthanide( III ) Ion by Sodium( I ) Ions

Autor:	José González, Magdalena Capó, Harry Adams
Rok vydání:	2004
Předmět:	Lanthanide Metal ions in aqueous solution Inorganic chemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Alkali metal Ion Inorganic Chemistry Metal Crystallography Transmetalation chemistry visual_art visual_art.visual_art_medium Scandium
Zdroj:	European Journal of Inorganic Chemistry. 2004:3405-3408
ISSN:	1099-0682 1434-1948
DOI:	10.1002/ejic.200400243
Popis:	Mononuclear triple-stranded helicate complexes ML3 (M = Sc3+, La3+, Sm3+, Yb3+) were self-assembled and structurally characterized by NMR spectroscopy and high-resolution mass spectrometry. The solid-state structure of the ytterbium complex was determined by X-ray crystallography. The core lanthanide metal ion was replaced quantitatively by three sodium ions. Homo- and heterotrinuclear complexes containing the alkali metal ions Li+ and Na+ were obtained from the mononuclear lanthanide complexes. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::81b29bdd1da8a96cdbc29d140a801b4c https://doi.org/10.1002/ejic.200400243 Zobrazit plný text záznamu Plný text