The Introduction of Asymmetry into Alkyl-Decorated Fréchet-Type Dendrons

Autor:	Bianca A. Hermann, Catherine E. Housecroft, Edwin C. Constable, Michael S. Malarek, Lukas J. Scherer, Stefan Graber
Rok vydání:	2008
Předmět:	chemistry.chemical_classification Chemistry Stereochemistry media_common.quotation_subject Dendrimer Organic Chemistry Physical and Theoretical Chemistry Asymmetry Mass spectrometric Medicinal chemistry Alkyl media_common
Zdroj:	European Journal of Organic Chemistry. 2008:2644-2651
ISSN:	1099-0690 1434-193X
DOI:	10.1002/ejoc.200800134
Popis:	A strategy for the introduction of asymmetry into Frechet-type dendrons bearing n-alkyl chains is described. Starting from a methyl 3,5-dihydroxybenzoate core, 3,5-bis(octyloxyphenyl)methoxy and 3,5-bis(alkoxyphenyl)methoxy units are introduced in a stepwise manner. The method is illustrated by the syntheses of four representative compounds having mixed n-octyl/n-butyl, n-octyl/n-hexyl, n-octyl/n-heptyl and n-octyl/n-dodecyl substituents. The new compounds have been characterized by spectroscopic and mass spectrometric techniques.
Databáze:	OpenAIRE
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