A simple route to the synthesis of single crystalline copper metagermanate nanowires

Autor: C.G. Fan, H.S. Zhao, W. Tan, Qian-Feng Zhang, L.Z. Pei, Y.W. Chen, H.Y. Yu
Rok vydání: 2009
Předmět:
Zdroj: Materials Characterization. 60:1602-1606
ISSN: 1044-5803
DOI: 10.1016/j.matchar.2009.07.005
Popis: Single crystalline copper metagermanate (CuGeO 3 ) nanowires with the diameter of 30–300 nm and length of longer than 100 µm have been prepared by a simple hydrothermal deposition route. X-ray diffraction (XRD), selected area electron diffraction (SAED), high-resolution transmission electron microscopy (HRTEM) and Raman analyses confirm that the nanowires are orthorhombic single crystals with a main growth direction along . Room temperature photoluminescence (PL) measurement shows a strong blue emission peak at 442 nm with a broad emission band. The blue emission may be ascribed to radiative recombination of oxygen vacancies and oxygen–germanium vacancies. The formation process of CuGeO 3 nanowires is also discussed.
Databáze: OpenAIRE