Supramolecular compounds of chloroaquacomplexes [Mo3Q4(H2O)9−x Clx](4−x )+ (Q = S, Se; x = 2, 3, 5) with cucurbit[n]urils

Autor:	Denis G. Samsonenko, Elena V. Chubarova, Vladimir P. Fedin, Cristian Vicent, Maxim N. Sokolov
Rok vydání:	2006
Předmět:	Stereochemistry Hydrogen bond Supramolecular chemistry chemistry.chemical_element Crystal structure Adduct Inorganic Chemistry Crystallography chemistry Cucurbituril Molybdenum Materials Chemistry Cluster (physics) Physical and Theoretical Chemistry Cis–trans isomerism
Zdroj:	Journal of Structural Chemistry. 47:939-945
ISSN:	1573-8779 0022-4766
Popis:	The following adducts of cucurbit[6]uril and cucurbit[8]uril with triangular cluster chloroaquacomplexes have been prepared and characterized: {[Mo3S4(H2O)7Cl2]2(CB[6])}Cl4·13H2O (I), (H3O)2{[Mo3Se4×(H2O)6Cl3](CB[6])}Cl3·3.5H2O (II) and (H3O)2{[Mo3S4(H2O)4Cl5](CB[8])}Cl·14H2O (III). It is shown that the formation of complementary hydrogen bonds in the systems cucurbit[6]uril/[M3Q4(H2O)9−xClx](4−x)+ (x = 1–3) results in a selective isolation of isomers containing chlorine atom in the trans-position to the capping μ3-ligand. For large x, a selective inclusion of one or another form into the supramolecular compound is also affected by other factors (a system of hydrogen bonds, S⋯S and S…Cl interactions between cluster complexes, packing effects etc.).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8165fb4cf86b8a2831cf05b69d93dabe https://doi.org/10.1007/s10947-006-0411-8 Zobrazit plný text záznamu Plný text ve formátu PDF