Half-sandwich ruthenium(II) complexes containing biphenylamine based Schiff base ligands: Synthesis, structure and catalytic activity in amidation of various aldehydes
| Autor: | Veerasamy Nagalakshmi, Kasthuri Balasubramani, Veerappan Brindha, Raja Nandhini, Bellie Sundaram Krishnamoorthy |
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| Rok vydání: | 2020 |
| Předmět: |
Schiff base
010405 organic chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Solid state structure 0104 chemical sciences Ruthenium Catalysis Biphenylamine Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Single crystal |
| Zdroj: | Journal of Organometallic Chemistry. 912:121175 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2020.121175 |
| Popis: | New half-sandwich ruthenium (II) complexes [η6‒p-cymene)Ru (L1-3)Cl] (1–3) containing biphenylamine based Schiff base ligands (HL1-3) have been synthesized and characterized by analytical and spectroscopic methods. Additionally, the solid state structure of 2 has been determined by single crystal X-ray diffraction study. The complex 2 serves as a catalyst for the amidation of various aldehydes to amides in good yield. |
| Databáze: | OpenAIRE |
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