Lanthanide nitrate complexes of the redox active ligand (η5C5H4P(O)Ph2)2Fe

Autor:	John Fawcett, Eileen M. Buckley-Dhoot, Andrew W.G. Platt, Roman A. Kresinski
Rok vydání:	2009
Předmět:	Inorganic Chemistry Lanthanide Lanthanide contraction Crystallography Chemistry Ligand Lanthanide nitrate Materials Chemistry Redox active Physical and Theoretical Chemistry Electrochemistry Single crystal
Zdroj:	Polyhedron. 28:1497-1503
ISSN:	0277-5387
DOI:	10.1016/j.poly.2009.02.028
Popis:	The synthesis of complexes of (η5C5H4P(O)Ph2)2Fe = L with lanthanide nitrates is described. The single crystal X-ray structures for La(NO3)3L(μ-L)La(NO3)3L (1), [Eu(NO3)2L2]2[Eu(NO3)5] (2), [Ho(NO3)2L2]2[Ho(NO3)5] (3) and [Lu(NO3)2L2] NO3 (4) are reported. Trends in Ln–O bond distances cannot be explained by the lanthanide contraction alone. The cyclic-voltammetric (CV) oxidation–reduction behaviour of 1, 2, 4 and Dy(NO3)3L2 · 2H2O is described. This was reversible on a timescale of a few seconds in all cases. In our hands the CV behaviour of L also seemed reversible on this timescale, although attempted chemical oxidation of L led to the isolation of [FeL2(NO3)2]NO3 (5) which was characterised by X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::814a5d584bf68c0a37e8b6c0ec778280 https://doi.org/10.1016/j.poly.2009.02.028 Zobrazit plný text záznamu Full Text from ScienceDirect