N-heterocyclic carbene catalysed oxidative esterification of aliphatic aldehydes

Autor:	Armido Studer, Ramesh C. Samanta
Rok vydání:	2014
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Base (chemistry) Organic Chemistry Organic chemistry Rubidium carbonate Oxidative phosphorylation Carbene
Zdroj:	Org. Chem. Front.. 1:936-939
ISSN:	2052-4129
DOI:	10.1039/c4qo00164h
Popis:	N-heterocyclic carbene-catalyzed oxidative esterification of various aliphatic aldehydes is reported. A commercially available bisquinone is used as an external oxidant and rubidium carbonate is best suited as base to run these processes. With the novel method various aliphatic esters are directly obtained in good to excellent yields from the corresponding aldehydes and alcohols.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8141be37595baf0c03beb3c899b3c546 https://doi.org/10.1039/c4qo00164h Zobrazit plný text záznamu