Reactions of HNNO+ and NNOH+ ions with CH4 and NO as a function of relative kinetic energy

Autor:	N.D. Twiddy, J. Glosik, G. Javahery, E. E. Ferguson
Rok vydání:	1990
Předmět:	Arrhenius equation chemistry.chemical_classification Chemistry Analytical chemistry Protonation Mass spectrometry Kinetic energy Ion symbols.namesake Reaction rate constant Hydrocarbon symbols Proton affinity Physical chemistry Spectroscopy
Zdroj:	International Journal of Mass Spectrometry and Ion Processes. 98:225-233
ISSN:	0168-1176
DOI:	10.1016/0168-1176(90)80003-l
Popis:	Rate constants for the reaction of the two isomers of protonated N 2 O, HNNO + and NNOH + , with CH 4 and NO have been measured as a function of relative kinetic energy. The CH 4 measurements allow a determination of the proton affinity of N 2 O on N of 131.5 ± 1 kcal mol −1 and an isomeric energy difference of 6.2 ± 0.5 kcal mol −1 . This latter value should be compared with the recently obtained theoretical value of 7.1 kcal mol −1 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8120762d73d58e88fae5e27a0e2a6f2e https://doi.org/10.1016/0168-1176(90)80003-l Zobrazit plný text záznamu