Crystal and Molecular Structures of 3-Carboxypropyltriphenylphosphonium Diiodobromide

Autor:	G. G. Aleksandrov, Oleg A. Dyachenko, M. S. Chernov'yants, Olga N. Kazheva, S. S. Simonyan, E. O. Lykova
Rok vydání:	2003
Předmět:	Crystal Crystallography chemistry.chemical_compound chemistry Stability constants of complexes Bromide Hydrogen bond General Chemical Engineering Dimer Intermolecular force Cationic polymerization Molecule General Chemistry
Zdroj:	Russian Journal of Coordination Chemistry. 29:819-827
ISSN:	1070-3284
DOI:	10.1023/b:ruco.0000008392.20283.88
Popis:	Complexation in the 3-carboxypropyltriphenylphosphonium bromide–molecular iodine system in chloroform was studied. The maximum number of iodine molecules coordinated by 3-carboxypropyltriphenylphosphonium bromide was established by the spectrophotometric method using a function of the average-iodine number, and the stability constant of the complex was determined. The [(C6H5)3P(CH2)3COOH]BrI2 diiodobromide was studied by X-ray diffraction analysis. The characteristic feature of the crystalline salt was the formation of dimer associates: anionic associates were formed due to the Br···Br intermolecular interactions and cationic associates were formed due to the O···H–O hydrogen bonds. The data obtained were correlated to the results of quantum-chemical calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::810be4255be219421a6f1cd3a4605101 https://doi.org/10.1023/b:ruco.0000008392.20283.88 Zobrazit plný text záznamu Full text from SpringerLink