C N bond formation in alicyclic and heterocyclic compounds by amine-modified nanoclay
| Autor: | Zohre Zarnegar, Javad Safari, Majid Ahmadzadeh, Roghayeh Alizadeh |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Chemistry Organic Chemistry Bond formation 010402 general chemistry Heterogeneous catalysis 01 natural sciences 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Solvent chemistry.chemical_compound Alicyclic compound Montmorillonite Atom economy Reagent Organic chemistry Amine gas treating Spectroscopy |
| Zdroj: | Journal of Molecular Structure. 1144:58-65 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2017.05.004 |
| Popis: | In the current protocol, amine functionalized montmorillonite K10 nanoclay (NH 2 -MMT) was applied to catalyze the formation of C N bonds in the synthesis of azines and 2-aminothiazoles at room temperature. In comparison with the current methods of C N bond formation, this approach displays specific advantages include atom economy, clean conversion, design for energy efficiency, the use of nontoxic and heterogeneous catalyst, higher purity and yields, safer solvent and reagents for this organic transformation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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