Urothermal Synthesis of a Photoluminescent Coordination Polymer with Rutile Topology

Autor:	Qi-Dan Ling, Zi-Sheng Liu, E. Yang, Hong-Yan Li
Rok vydání:	2013
Předmět:	Thermogravimetric analysis Materials science Photoluminescence Polymers and Plastics Coordination polymer Crystal structure Topology Solvent chemistry.chemical_compound chemistry Rutile Materials Chemistry Molecule Topology (chemistry)
Zdroj:	Journal of Inorganic and Organometallic Polymers and Materials. 23:1023-1027
ISSN:	1574-1451 1574-1443
DOI:	10.1007/s10904-013-9868-z
Popis:	A new coordination polymer [Cd3(btc)2(e-urea)4].(e-urea)2 (1; btc = 1,3,5-benzenetricarboxylate; e-urea = ethyleneurea) has been urothermally synthesized using ethyleneurea hemihydrate as the solvent and exhibits (3,6)-connected rutile (rtl) topology. The structure of 1 consists of trinuclear Cd units and the btc linkers. Species 1 features a non-interpenetrating three-dimensional open framework with channels filled by the e-urea additives and guest molecules. The thermogravimetric behavior and photoluminescent property of 1 were studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::80f491388f7dd495fbc16e2ef556fac5 https://doi.org/10.1007/s10904-013-9868-z Zobrazit plný text záznamu Full text from SpringerLink