Time-resolved two-laser probe of chromium hexacarbonyl photodissociation dynamics

Autor:	Robert L. DeLeon, James F. Garvey, William R. Peifer
Rok vydání:	1992
Předmět:	chemistry.chemical_compound Chemical bond Chemistry Photodissociation General Engineering Analytical chemistry Metal carbonyl Physical and Theoretical Chemistry Ground state Fluorescence Chromium hexacarbonyl Dissociation (chemistry) Ion
Zdroj:	The Journal of Physical Chemistry. 96:6523-6526
ISSN:	1541-5740 0022-3654
Popis:	This paper discusses Cr(CO){sub 6} photodissociation using a time-resolved MPD/atomic fluorescence technique. Cr(CO){sub 4} appears more slowly when Cr(CO){sub 6} is cooled in a supersonic expansion due to slower internal conversion in Cr(CO){sub 5} following loss of the first CO ligand facilitated by low-energy OC-Cr-CO bending modes. 26 refs., 1 fig., 1 tab.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::80f2184f8808600caf95111311a83a6c https://doi.org/10.1021/j100195a003 Zobrazit plný text záznamu