Activation volumes and solvent effects on bimolecular reactions of low-spin d6 complexes

Autor:	John Burgess, Robert Sherry, Andrew J. Duffield
Rok vydání:	1980
Předmět:	chemistry.chemical_compound chemistry Cyanide Inorganic chemistry Molecular Medicine Desolvation Solvent effects Photochemistry Spin (physics)
Zdroj:	Journal of the Chemical Society, Chemical Communications. :350
ISSN:	0022-4936
DOI:	10.1039/c39800000350
Popis:	Activation volumes for reactions of [Fe(4-Me-phen)3]2+ with cyanide and with peroxodisulphate, and of Mo(bipy)(CO)4 with cyanide in various solvents suggest that cyanide or peroxodisulphate desolvation is a dominant feature in transition state formation.
Databáze:	OpenAIRE
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