Relationship between stimulated emission and reaction mechanism in chemical lasers utilizing mixtures of chlorine flourides and hydrogen

Autor:	S Ya Pshezhetskiĭ, N F Chebotarev
Rok vydání:	1976
Předmět:	Autocatalysis Reaction mechanism Hydrogen Chemistry General Engineering Chlorine Molecule chemistry.chemical_element Qualitative inorganic analysis Stimulated emission Photochemistry Intermediate product
Zdroj:	Soviet Journal of Quantum Electronics. 6:1214-1217
ISSN:	0049-1748
DOI:	10.1070/qe1976v006n10abeh011930
Popis:	An analysis is made of the principal elementary processes resulting in stimulated emission from ClF3+H2 and ClF5+H2 systems. A study of pulsed stimulated emission from HF and HCl in mixtures containing also HCl, Cl2, and ClF shows that the intermediate product ClF is a part of a laser reaction chain. The process H+ClF2→HCl*+F is much faster than H+ClF3 or H+ClF5. It is found that "autocatalysis" by HCl molecules, which are also an intermediate product, is possible in the ClF5+H2 system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::80cf697f64b42436e303efa18d3728ad https://doi.org/10.1070/qe1976v006n10abeh011930 Zobrazit plný text záznamu