Phase-controlled synthesis of thermally stable nitrogen-doped carbon supported iron catalysts for highly efficient Fischer-Tropsch synthesis
| Autor: | Jung-Il Yang, Shin Wook Kang, Jin Hee Lee, Ji Chan Park, Heon Jung, Hyunkyung Choi, Dong Hyun Chun, Hack-Keun Lee, Heon-Do Jeong, Min Hye Youn, Geun Bae Rhim, Chul Sung Kim |
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| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Materials science Nanoparticle chemistry.chemical_element Fischer–Tropsch process 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Chemical synthesis Atomic and Molecular Physics and Optics 0104 chemical sciences Catalysis Hydrocarbon chemistry Chemical engineering Phase (matter) General Materials Science Electrical and Electronic Engineering 0210 nano-technology Dispersion (chemistry) Carbon |
| Zdroj: | Nano Research. 12:2568-2575 |
| ISSN: | 1998-0000 1998-0124 |
| Popis: | Iron-based nanoparticles with uniform and high particle dispersion, which are supported on carbon structures, have been used for various applications. However, their preparation still suffers from complicated synthesis involving multiple steps and from the high price of precursors and solvents. In the present work, a new carbon encapsulated iron-carbide nanoparticle supported on nitrogen-doped porous carbon (Fe5C2@C/NPC) structure was introduced. It was made using a simple solid-state reaction with sequential thermal treatments. Fe5C2@C/NPC is a highly active and stable catalyst for the high-temperature Fischer-Tropsch synthesis reaction. It showed very high hydrocarbon productivity (4.71 gHC·gcat−1·h−1) with high CO conversions (up to 96%). |
| Databáze: | OpenAIRE |
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