Solid-state FDMR from sundry poly(oxyethylene) alkylphenyl ethers: a verification of the single-step electron tunneling as a cause of the charge mobility in frozen solids at 4-30 K

Autor:	I. A. Shkrob, A. D. Trifunac
Rok vydání:	1993
Předmět:	Electron transfer Electron mobility Aqueous solution Radical ion Resonance fluorescence Chemistry Radiolysis General Engineering Physical chemistry Physical and Theoretical Chemistry Quantum tunnelling Fluorescence spectroscopy
Zdroj:	The Journal of Physical Chemistry. 97:13298-13307
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100152a038
Popis:	Observations of the time-resolved fluorescence-detected magnetic resonance (FDMR) from bridged radical ion pairs generated by pulse radiolysis of micellar aqueous and homogeneous alcohol solutions of poly(oxyethylene) (chain length 5-40) alkylphenyl ethers at 430 K are reported. Theoretical analysis of the spectra favors single-step through-bond electron tunneling as a mechanism of the geminate recombination in the pairs at these low temperatures
Databáze:	OpenAIRE
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