A non-interpenetrating 3D porous metal-organic framework (MOF) holding rutile-type topology containing Cu4 secondary building units

Autor:	Yu-mei Song, Xiao-zhao Tian, Zhen-wei Liao, Hai-xiao Huang, Shu-juan Liu, Feng Luo, Xue-Feng Feng, Gong-ming Sun
Rok vydání:	2012
Předmět:	chemistry.chemical_classification Porous metal Secondary building unit Materials science Mineralogy Polymer Inorganic Chemistry Thermogravimetry chemistry Chemical engineering Rutile Materials Chemistry Physical and Theoretical Chemistry Porosity Topology (chemistry) Thermal methods
Zdroj:	Inorganic Chemistry Communications. 16:43-46
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2011.11.026
Popis:	In this work, we obtained a rarely three-dimensional porous Cu(II) MOF, namely [Cu2(BTC)(OH)(Me2NH)⋅ 2H2O ⋅ DMF]n (Me2NH—dimethylamine, [BTC3 −—1,3,5-benzenetricarboxylate, DMF—N,N′-dimethylformamide], by solvo(hydro)thermal method. This polymer was characterized by single-crystal X-ray diffraction, EA, and thermogravimetry analysis. The outstanding structural feature of it is the coordination of Me2NH—a hydrolysate from DMF, and the non-interpenetrating porous rutile net. Further, based on the investigation of literatures, we also discussed the architectonics involving common Cu4 secondary building unit (SBU) in detail.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::80b0982ef6a2260c8f4634c843f01bfd https://doi.org/10.1016/j.inoche.2011.11.026 Zobrazit plný text záznamu Full Text from ScienceDirect