Circular dichroism spectroscopy at interfaces: a surface second harmonic generation study

Autor:	T. Petralli-Mallow, T. M. Wong, Jeff D. Byers, H. I. Yee, Janice M. Hicks
Rok vydání:	1993
Předmět:	Circular dichroism Chemistry business.industry General Engineering Dichroic glass Helicity Molecular physics Spectral line Molecular dynamics Optics Vibrational circular dichroism Surface second harmonic generation Physical and Theoretical Chemistry business Spectroscopy
Zdroj:	The Journal of Physical Chemistry. 97:1383-1388
ISSN:	1541-5740 0022-3654
Popis:	A new technique which links the phenomenon of surface second harmonic generation (SHG) with circular dichroism (CD) spectroscopy is introduced. SHG spectra of chiral molecules (2,2'-dihydroxy-1,1'-binaphthyl) adsorbed at the air/water interface are dependent on the helicity of the incident circularly polarized beam. Moreover, the magnitude of the circular dichroic effect is 10 3 times greater than that observed in ordinary CD spectroscopy. Several factors including molecular orientation at the surface are considered as possible explanations for this enhancement
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::809aaa32389fbfcb9836bf78a4f86a90 https://doi.org/10.1021/j100109a022 Zobrazit plný text záznamu