| Popis: |
This work deals with the quantum-mechanical calculation of the temperature-dependent mobility of ionic lithium atoms diffusing in their parent gas. The computation of the quantal phase shifts in connection with the gerade and ungerade potential–energy curves, through which Li + approaches Li(2s) , leads to the computation of the charge-transfer and diffusion cross sections. The behavior of the coefficients of diffusion and mobility with temperature is also examined. Throughout this work, the isotopic effects in the 7 Li + – 7 Li and 6 Li + – 7 Li collisions are emphasized. |
