Halogenierung und Acyloxylierung von N-Cyclohex-2-en-1-on-3-yl-aminosäuren / Halogenation and Acyloxylation of N-Cyclohex-2-en-1-on-3-yl-amino Acids

Autor:	Irene Wippermann, Gerhard G. Habermehl, Susanne tom Dieck, Hans C. Krebs
Rok vydání:	1991
Předmět:	chemistry.chemical_classification chemistry Halogenation Organic chemistry General Chemistry Amino acid
Zdroj:	Zeitschrift für Naturforschung B. 46:1415-1420
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-1991-1020
Popis:	Secondary enaminones 2 are easily halogenated to yield the so far unknown halogenides 3,4 and 5. Acyloxylation of enaminones 2 by dibenzoylperoxide leads to benzoyloxylated substances 13, which also have not been described jet. Bisacylated products could not be traced. Only the rearranged compounds 14 could be isolated. 14b showed cytotoxic activity.
Databáze:	OpenAIRE
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