Effect of 1,1,5-trihydroperfluoropentanol on the structure of unoriented poly(ɛ-caproamide) films

Autor:	Krasnov Aleksandr P, Ya. V. Zubavichus, N. A. Storozhakova, V. V. Priimak, Ivan A. Novakov
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Materials science Polymers and Plastics Formic acid Film plane Trans conformation Polymer chemistry.chemical_compound chemistry Caproamide Polymer chemistry Materials Chemistry Ceramics and Composites Perpendicular Molecule Macromolecule
Zdroj:	Polymer Science Series B. 49:70-74
ISSN:	1555-6123 1560-0904
Popis:	A change in the X-ray patterns of unoriented poly(ɛ-caproamide) films cast from poly(ɛ-caproamide) solutions in formic acid in the presence of 1,1,5-trihydroperfluoropentanol has been examined. It has been shown that the polyfluorinated alcohol increases the proportion of polymer molecules in the planar trans conformation owing to their transition from the gauche conformation constituting the amorphous phase and facilitates formation of hydrogen-bonded layers of macromolecules oriented perpendicular to the film plane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::805ce20f2e6ac89f3b8d27db38bad9ac https://doi.org/10.1134/s1560090407030049 Zobrazit plný text záznamu Full text from SpringerLink