The Elusive 16-Electron Cp*M(NO)Me2 (M = Mo, W) Complexes and Their Spontaneous Conversions to Cp*M(NMe)(O)Me Isomers
Autor: | Peter Legzdins, McNeil Ws, Daff Pj, Sharp Wb |
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Rok vydání: | 2001 |
Předmět: | |
Zdroj: | Journal of the American Chemical Society. 123:6272-6282 |
ISSN: | 1520-5126 0002-7863 |
DOI: | 10.1021/ja002856+ |
Popis: | Treatment of [Cp*Mo(NO)Cl(μ-Cl)]2 with magnesium (Me2Mg·dioxane, MeMgCl) or aluminum (Me3Al) methylating reagents affords the known compound [Cp*Mo(NO)Me(μ-Cl)]2 (1). Similar treatment of the dichl... |
Databáze: | OpenAIRE |
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