The Elusive 16-Electron Cp*M(NO)Me2 (M = Mo, W) Complexes and Their Spontaneous Conversions to Cp*M(NMe)(O)Me Isomers

Autor: Peter Legzdins, McNeil Ws, Daff Pj, Sharp Wb
Rok vydání: 2001
Předmět:
Zdroj: Journal of the American Chemical Society. 123:6272-6282
ISSN: 1520-5126
0002-7863
DOI: 10.1021/ja002856+
Popis: Treatment of [Cp*Mo(NO)Cl(μ-Cl)]2 with magnesium (Me2Mg·dioxane, MeMgCl) or aluminum (Me3Al) methylating reagents affords the known compound [Cp*Mo(NO)Me(μ-Cl)]2 (1). Similar treatment of the dichl...
Databáze: OpenAIRE