Highly Efficient Redox Isomerization of Allylic Alcohols and Transfer Hydrogenation of Ketones and Aldehydes Catalyzed by Ruthenium Complexes
| Autor: | Chak Po Lau, Pei Nian Liu, Kun Dong Ju |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Allylic rearrangement organic chemicals Noyori asymmetric hydrogenation chemistry.chemical_element General Chemistry Transfer hydrogenation Aldehyde Redox Combinatorial chemistry Catalysis Ruthenium chemistry otorhinolaryngologic diseases Organic chemistry Isomerization |
| Zdroj: | Advanced Synthesis & Catalysis. 353:275-280 |
| ISSN: | 1615-4150 |
| DOI: | 10.1002/adsc.201000667 |
| Popis: | A dicationic dichloro-bipyridine-ruthenium complex shows very high catalytic activity in redox isomerization of allylic alcohols but a relatively low one in transfer hydrogenation of ketones; surprisingly, the analogous dimethyl-bipyridine-ruthenium complex shows reverse catalytic activities in the two reactions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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