Polymerization of monoallyl silicon derivatives in presence of the catalyst system (i-C4H9)3Al+TiCl4

Autor:	N. S. Nametkin, S. G. Durgar'yan, V. I. Zav'yalov, A. V. Topchiev, Ch'iu Hsiao-p'ei
Rok vydání:	1963
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Silicon chemistry Chemical engineering Polymerization Yield (chemistry) Titanium tetrachloride chemistry.chemical_element Organic chemistry General Chemistry Polymer Catalysis
Zdroj:	Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 12:244-249
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00846390
Popis:	1. By the polymerization of allyltrimethylsilane and of allyldimethylphenylsilane in presence of the complex catalyst (i-C4H9)3 Al+TiCl4, high-molecular crystalline polyallyltrimethylsilane and polyallyldimethylphenylsilane can be obtained. 2. A study was made of the effect of the relative amounts of triisobutylaluminum and titanium tetrachloride on the yield and properties of the solid polymers.
Databáze:	OpenAIRE
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