A chiral probe useful for optical resolution and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids
| Autor: | Hisashi Uda, Shinji Murai, T. Soutome, Nobuyuki Harada |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
chemistry.chemical_classification
Chiral auxiliary Stereochemistry Carboxylic acid Organic Chemistry Resolution (electron density) Absolute configuration Crystal structure Catalysis Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry X-ray crystallography Molecule Physical and Theoretical Chemistry Cyclophane |
| Zdroj: | Tetrahedron: Asymmetry. 4:1755-1758 |
| ISSN: | 0957-4166 |
| Popis: | (1S,2R,4R)-(−)-2,10-Camphorsultam is a very useful chiral probe for optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. The absolute configurations of 2,6-dimethylspiro[3.3]heptane-2,6-dicarboxylic acid and [2.2]paracyclophane-4-carboxylic acid are determined. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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