Fabrication of Nitrogen-Doped Graphene Decorated with Organophosphor and Lanthanum toward High-Performance ABS Nanocomposites
| Autor: | Deman Han, Pingan Song, Qidong Yan, Chao Gao, Yanxian Jin, Guobo Huang |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Fabrication Nanocomposite Materials science Graphene Rare earth Oxide chemistry.chemical_element 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis law.invention chemistry.chemical_compound Chemical engineering chemistry law Lanthanum General Materials Science 0210 nano-technology |
| Zdroj: | ACS Applied Nano Materials. 1:3204-3213 |
| ISSN: | 2574-0970 |
| DOI: | 10.1021/acsanm.8b00411 |
| Popis: | Despite substantial advances, it remains imperative but challenging to develop high-performance polymer/graphene nanocomposites combining with excellent mechanical, thermal, and fire-retardant properties. In this work, a novel kind of graphene-based multifunctional nanofiller (La@PN-RGO) was fabricated via the nitrogen doping and the decoration with organophosphorus and lanthanum based on graphene oxide, which is then incorporated into acrylonitrile–butadiene–styrene (ABS) resin via melt blending to obtain resultant ABS nanocomposites. As expected, the La@PN-RGO nanosheets were well dispersed in ABS composites. Attractively, with only 1.0 wt % of La@PN-RGO incorporated into ABS matrix, the peak heat release rate (PHRR) and total smoke production (TSP) were significantly reduced by 38% and 36%, which is much superior to its counterparts at the same nanofillers loading level. The notably enhanced fire safety was primarily attributed to the rare earth catalysis accompanied by the lamellae blocking effect and... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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