ChemInform Abstract: Amide-Directed Alkenylation of sp2C-H Bonds Catalyzed by a Cationic Rh(I)/BIPHEP Complex under Mild Conditions: Dramatic Rate Acceleration by a 1-Pyrrolidinecarbonyl Group

Autor:	Ken Tanaka, Yousuke Otake, Yu Shibata, Masao Hirano
Rok vydání:	2009
Předmět:	Reaction conditions chemistry.chemical_compound chemistry Group (periodic table) Amide Cationic polymerization Regioselectivity chemistry.chemical_element General Medicine Medicinal chemistry Rhodium Catalysis
Zdroj:	ChemInform. 40
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200925062
Popis:	A cationic rhodium(I)/BIPHEP complex catalyzes amide-directed regioselective alkenylations of olefinic or aromatic sp2 C−H bonds in good yields under mild reaction conditions. The use of a 1-pyrrolidinecarbonyl group as a directing group dramatically accelerates the reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7fce5437f54fd9052b17b36ba74cf441 https://doi.org/10.1002/chin.200925062 Zobrazit plný text záznamu Plný text