Efficient catalysts for benzene alkylation with olefins
| Autor: | I. M. Kolesnikov, S. I. Kolesnikov, Evgenii Ivanov, Vladimir A. Vinokurov, V. A. Lyubimenko, Pavel A. Gushchin |
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| Rok vydání: | 2016 |
| Předmět: |
Ethylene
010405 organic chemistry Process Chemistry and Technology Quantum chemical computations General Chemistry Alkylation 010402 general chemistry 01 natural sciences Acceptor Chloride Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry medicine Organic chemistry Selectivity Benzene medicine.drug |
| Zdroj: | Catalysis Communications. 82:1-6 |
| ISSN: | 1566-7367 |
| DOI: | 10.1016/j.catcom.2016.04.001 |
| Popis: | The experimental data of benzene alkylation with ethylene and propylene in the presence of methyl and ethylchlorosilanes are presented in this article. The catalytic activity series are determined for the methyl and ethylchlorosilanes. These compounds are found to demonstrate high catalytic activity and selectivity in the alkylation reactions and can be used in place of aluminum chloride. The computational study reveals the linear dependence between the charges, acceptor capacities and activities of the catalysts in the alkylation reactions. |
| Databáze: | OpenAIRE |
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