Stearic acid hydrodeoxygenation over Pd nanoparticles embedded in mesoporous hypercrosslinked polystyrene

Autor:	Valentin N. Sapunov, Esther M. Sulman, Mikhail G. Sulman, Alexander I. Sidorov, Valentina G. Matveeva, Päivi Mäki-Arvela, Johan Wärnå, Dmitry Yu. Murzin, Barry D. Stein, Аntonina А. Stepacheva
Rok vydání:	2017
Předmět:	010405 organic chemistry Chemistry General Chemical Engineering Induction period Inorganic chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound Physisorption Chemisorption Polystyrene Stearic acid Mesoporous material Hydrodeoxygenation
Zdroj:	Journal of Industrial and Engineering Chemistry. 46:426-435
ISSN:	1226-086X
DOI:	10.1016/j.jiec.2016.11.013
Popis:	Stearic acid hydrodeoxygenation into n-heptadecane on the catalyst containing Pd nanoparticles incorporated in the hypercrosslinked polystyrene matrix was studied. The used catalysts were characterized using TEM, CO chemisorption, low-temperature nitrogen physisorption and XPS. A clear hydrogen pressure dependent induction period was noticed. Kinetic regularities were studied for the indicated reaction in the presence of polymer based catalysts. A mathematical model for decarboxylation was suggested which was able to adequately describe experimental data at different temperatures, hydrogen pressures and initial concentrations of stearic acid. Kinetic constants were calculated and their statistical analysis was performed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7fc0ab52ce80be013f2b89c7adad384a https://doi.org/10.1016/j.jiec.2016.11.013 Zobrazit plný text záznamu Full Text from ScienceDirect