An isomer of the endohedral metallofullerene Sc3N@C80 with D5h symmetry

Autor:	Harry C. Dorn, Erick B. Iezzi, Aline Demortier, James C. Duchamp, Kerra R. Fletcher, T. E. Glass, Daniel Dorn
Rok vydání:	2003
Předmět:	Crystallography chemistry.chemical_compound Fullerene Chemistry Stereochemistry Carbon-13 Metallofullerene Mass spectrum General Physics and Astronomy Physical and Theoretical Chemistry Symmetry (geometry) Carbon-13 NMR Mass spectrometry
Zdroj:	Chemical Physics Letters. 375:655-659
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(03)00844-3
Popis:	The discovery of a new isomer of the endohedral metallofullerene Sc3N@C80 is reported. 13C labeled (∼9%) Sc3N@C80 has been synthesized and has been characterized by HPLC, mass spectroscopy and 13C NMR data. The 13C NMR spectrum shows six peaks with a 1:2:2:1:1:1 ratio that are assigned to the D5h isomer. The results of theoretical calculations are also reported for the Ih and D5h isomers of Sc3N@C80.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7fbc286c8b6b64d542a595ffabf9c932 https://doi.org/10.1016/s0009-2614(03)00844-3 Zobrazit plný text záznamu Full Text from ScienceDirect