Application of a Batch Microwave Unit for Scale-Up of Alkoxycarbonylation Reactions Using a Near-Stoichiometric Loading of Carbon Monoxide

Autor:	Nicholas E. Leadbeater, Mauro Iannelli, Fabio Bergamelli, Stefano Paravisi, Chad M. Kormos
Rok vydání:	2009
Předmět:	chemistry.chemical_compound Chemistry Microwave heating Organic Chemistry Inorganic chemistry SCALE-UP Iodobenzene Batch processing Physical and Theoretical Chemistry Microwave Stoichiometry Carbon monoxide
Zdroj:	Organic Process Research & Development. 13:634-637
ISSN:	1520-586X 1083-6160
DOI:	10.1021/op800296d
Popis:	The ethoxycarbonylation of iodobenzene was performed on the 1 mol scale in batch mode using microwave heating. The reaction was performed using both an excess and a near stoichiometric loading of carbon monoxide, comparable yields being obtained. Six different alkoxycarbonylation reactions were then performed simultaneously on the 50 mmol scale using a near-stoichiometric loading of carbon monoxide with excellent conversions in each case.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7f9cee53a160b8cff22ac2d05695d98d https://doi.org/10.1021/op800296d Zobrazit plný text záznamu