Neutron powder diffraction study of (Co, Ti)-substituted fine-particle Ba-hexaferrite
Autor: | Kiril Krezhov, Erzsébet Sváb, Zoltán Somogyvári, Françoise Bourée, I. Nedkov, Gy. Mészáros |
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Rok vydání: | 2002 |
Předmět: | |
Zdroj: | Applied Physics A: Materials Science & Processing. 74:s1086-s1088 |
ISSN: | 1432-0630 0947-8396 |
Popis: | A neutron-diffraction study was performed on micro- and nanocrystalline BaFe10.3Co0.85Ti0.85O19 samples prepared by soft chemistry. Substitution and grain-size effects on the crystal structure were analysed in the P63/mmc space group using Rietveld refinement. It was established that the (Co2+, Ti4+) substitution causes significant distortions in the local oxygens surrounding ferric cation sites, while the grain-size effect on the structural parameters is considerably smaller. |
Databáze: | OpenAIRE |
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