Neutron powder diffraction study of (Co, Ti)-substituted fine-particle Ba-hexaferrite

Autor: Kiril Krezhov, Erzsébet Sváb, Zoltán Somogyvári, Françoise Bourée, I. Nedkov, Gy. Mészáros
Rok vydání: 2002
Předmět:
Zdroj: Applied Physics A: Materials Science & Processing. 74:s1086-s1088
ISSN: 1432-0630
0947-8396
Popis: A neutron-diffraction study was performed on micro- and nanocrystalline BaFe10.3Co0.85Ti0.85O19 samples prepared by soft chemistry. Substitution and grain-size effects on the crystal structure were analysed in the P63/mmc space group using Rietveld refinement. It was established that the (Co2+, Ti4+) substitution causes significant distortions in the local oxygens surrounding ferric cation sites, while the grain-size effect on the structural parameters is considerably smaller.
Databáze: OpenAIRE