Kinetics and mechanism of oxidation of cyclopentanone by N-bromosuccinimide

Autor:	S. P. Mushran, A. K. Bose, J. N. Tiwari
Rok vydání:	1976
Předmět:	Hydrogen Chemistry Kinetics Inorganic chemistry Mercuric acetate chemistry.chemical_element General Chemistry Cyclopentanone Photochemistry chemistry.chemical_compound Succinimide Ionic strength Methanol N-Bromosuccinimide
Zdroj:	Monatshefte f�r Chemie. 107:1021-1027
ISSN:	1434-4475 0026-9247
DOI:	10.1007/bf00904492
Popis:	N-bromosuccinimide oxidation of cyclopentanone in acidic media in presence of mercuric acetate has been made. A zero order dependance to N-bromosuccinimide and a first order dependence to cyclopentanone and hydrogen ion concentration has been observed. Ionic strength, mercuric acetate and succinimide has negligible effect while methanol addition has a positive effect. Various rate parameters have been computed and 1,2-cyclopentanedione identified as the end product. A suitable mechanism in confirmity with the above observations has been proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7f810d8055a3221f9ddf73608ad1ba14 https://doi.org/10.1007/bf00904492 Zobrazit plný text záznamu Full text from SpringerLink