ZnO formation through decomposition of zinc bis(ethyl acetoacetate) by steaming treatment
| Autor: | Ryohei Hayami, Nagato Endo, Kazuki Yamamoto, Takahiro Gunji, Yuta Miyase |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Steaming chemistry.chemical_element Substrate (chemistry) 02 engineering and technology General Chemistry Zinc 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Decomposition 0104 chemical sciences Electronic Optical and Magnetic Materials Biomaterials chemistry.chemical_compound chemistry Impurity Ethyl acetoacetate Materials Chemistry Ceramics and Composites Thin film 0210 nano-technology Nuclear chemistry Wurtzite crystal structure |
| Zdroj: | Journal of Sol-Gel Science and Technology. 91:255-260 |
| ISSN: | 1573-4846 0928-0707 |
| DOI: | 10.1007/s10971-019-05043-x |
| Popis: | Zinc bis(ethyl acetoacetate) (Zn(etac)2) was steamed with water vapor at various temperatures (40–70 °C). A portion of the ethyl acetoacetato group was dissociated upon steaming Zn(etac)2 at 40 °C. However, zinc oxide (ZnO) was not formed. On steaming at 50 °C, the ethyl acetoacetato group was completely removed. The Zn(etac)2 steamed at 50 °C was attributed to the wurtzite ZnO, but impurity was contaminated. Zn(etac)2 steamed at 60–70 °C was converted into pure wurtzite ZnO powder. The Zn(etac)2 could be decomposed by water vapor; interestingly, wurtzite ZnO powder was formed from Zn(etac)2 by steaming treatment at low temperature. Moreover, a Zn(etac)2 solution was coated on a glass substrate followed by steaming at 70 °C; a thin film showed a transparency and a flat surface. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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