Multiple C−F Bond Activation: Remarkable 4 to 4 Bond-Breaking/Bond-Making Reactions of Nb+ with Hexafluoro- and Tetrafluorobenzene

Autor:	Alwin Cunje, Diethard K. Bohme, and Alan C. Hopkinson, Gregory K. Koyanagi, Doina Caraiman
Rok vydání:	2002
Předmět:	Inorganic Chemistry Reaction rate Chemistry Intramolecular force Bond Organic Chemistry Fluorine chemistry.chemical_element Physical and Theoretical Chemistry Bond breaking Photochemistry Mass spectrometric
Zdroj:	Organometallics. 21:4293-4296
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om020527f
Popis:	Mass spectrometric reaction rate measurements are reported that show the remarkable occurrence of the breaking of four C−F bonds and the formation of four new Nb+−F bonds in gas-phase collisions of Nb+ with hexafluoro- and tetrafluorobenzene. A mechanism involving sequential intramolecular fluorine pick-up is proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7f5fef33f4b77370138f249495fa03db https://doi.org/10.1021/om020527f Zobrazit plný text záznamu