Benzene, Toluene, and Xylene Transport through UiO-66: Diffusion Rates, Energetics, and the Role of Hydrogen Bonding
| Autor: | Diego Troya, Amanda J. Morris, John R. Morris, Tyler G. Grissom, Pavel M. Usov, Conor H. Sharp |
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| Rok vydání: | 2018 |
| Předmět: |
Materials science
Hydrogen bond Diffusion Xylene 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Toluene Isothermal process 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound General Energy Adsorption chemistry Physical chemistry Physical and Theoretical Chemistry 0210 nano-technology Benzene Spectroscopy |
| Zdroj: | The Journal of Physical Chemistry C. 122:16060-16069 |
| ISSN: | 1932-7455 1932-7447 |
| DOI: | 10.1021/acs.jpcc.8b03356 |
| Popis: | The high-energy demand of benzene, toluene, and xylene (BTX) separation highlights the need for improved nonthermal separation techniques and materials. Because of their high surface areas, tunable structures, and chemical stabilities, metal–organic frameworks (MOFs) are a promising class of materials for use in more energy efficient, adsorption-based separations. In this work, BTX compounds in the pore environment of UiO-66 were systematically examined using in situ infrared (IR) spectroscopy to understand the fundamental interactions that influence molecular transport through the MOF. Isothermal diffusion experiments revealed BTX diffusivities between 10–8 and 10–12 cm2 s–1, where the rate follows the trend: o-xylene < m-xylene < p-xylene. Corresponding activation energies of diffusion (Ediff) were determined to be 44 kJ mol–1 for the xylene isomers and 34 kJ mol–1 for both benzene and toluene, with the diffusion-limiting barrier identified to be molecular passage through the small triangular pore apert... |
| Databáze: | OpenAIRE |
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