Toward N-heterocyclic carbene stabilized zinc sulfides
| Autor: | Michael J. Ferguson, Samuel R. Baird, Matthew M. D. Roy, Eric Rivard |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Partial hydrolysis Sulfide 010405 organic chemistry chemistry.chemical_element General Chemistry Zinc 010402 general chemistry 01 natural sciences Zinc sulfide Medicinal chemistry 0104 chemical sciences chemistry.chemical_compound chemistry Cluster (physics) Structural motif Carbene |
| Zdroj: | Mendeleev Communications. 31:173-175 |
| ISSN: | 0959-9436 |
| Popis: | A series of N-heterocyclic carbene (NHC) supported group 12 acetate complexes were prepared and their use as building blocks toward soluble group 12 sulfide precursors was explored. The highly moisture-sensitive NHC-ligated zinc dithiolato complex [(IPr)Zn(SSiMe3)2] was also synthesized [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene], and its partial hydrolysis gave the dianionic zinc sulfide cluster [Zn3(μ3-S)(μ2-SSiMe3)3(SSiMe3)3]2−, which contained a rare example of a Zn3S structural motif. This preliminary observation indicates that the future growth of related metallosulfide clusters from [(IPr)Zn(SSiMe3)2] should be possible. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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