α-Diimine synthesis via titanium-mediated multicomponent diimination of alkynes with C-nitrosos
| Autor: | Connor W. Frye, Dominic T. Egger, Errikos Kounalis, Adam J. Pearce, Yukun Cheng, Ian A. Tonks |
|---|---|
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Chemical Science. 13:1469-1477 |
| ISSN: | 2041-6539 2041-6520 |
| Popis: | Alkyne diimination to unsymmetric α-diimines can be achieved via multicomponent reaction of Ti imidos and C-nitrosos. C-nitroso [4 + 2] cycloaddition across a diazatitanacyclohexadiene initiates cascading retrocycloadditions, liberating the α-diimine. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|