Kinetic analysis of diethylbenzene-benzene transalkylation over faujasite Y
Autor: | D. Louhibi, L.M. Tiako Ngandjui, Fernand C. Thyrion |
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Rok vydání: | 1997 |
Předmět: |
Chemistry
Process Chemistry and Technology General Chemical Engineering Batch reactor Kinetics Kinetic analysis Energy Engineering and Power Technology General Chemistry Faujasite engineering.material Ethylbenzene Industrial and Manufacturing Engineering chemistry.chemical_compound engineering Physical chemistry Organic chemistry Transalkylation Benzene Selectivity |
Zdroj: | Chemical Engineering and Processing: Process Intensification. 36:133-141 |
ISSN: | 0255-2701 |
DOI: | 10.1016/s0255-2701(96)04179-7 |
Popis: | The thermodynamics and kinetics of the diethylbenzene-benzene transalkylation have been studied in liquid phase over faujasite Y in a batch reactor. The reactions were conducted at several temperatures between 423 and 513 K. The main product of the reaction was ethylbenzene. When the molar ratio of benzene over diethylbenzene was greater than five, a selectivity in ethylbenzene greater than 90% was found. The initial rates showed that the transalkylation reaction followed a first order mechanism. A kinetic model is proposed. (C) 1997 Elsevier Science S.A. |
Databáze: | OpenAIRE |
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