Determination of the rate constant of the elementary reaction H+ClF→HCl*+F

Autor:	S Ya Pshezhetskiĭ, N F Chebotarev, Leonid I. Trakhtenberg
Rok vydání:	1976
Předmět:	Reaction rate constant Materials science law Torr Elementary reaction General Engineering Analytical chemistry Molecule Stimulated emission Atmospheric temperature range Constant (mathematics) Laser law.invention
Zdroj:	Soviet Journal of Quantum Electronics. 6:1403-1406
ISSN:	0049-1748
DOI:	10.1070/qe1976v006n12abeh012536
Popis:	The rate constant of the elementary reaction H + ClH→HCl* + F was found from an analysis of the delay times of the stimulated emission due to the P2(3) and P2(5) transitions in the HF and HCl molecules, respectively, which occurred in a ClF–H2 laser. This constant was found to be 0.13 ±0.015 μsec–1·Torr–1 = (3.7±0.4)× 10–12 cm3/sec in the temperature range 300–400°K.
Databáze:	OpenAIRE
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